Gabriel Martinelli was an unused substitute as Brazil saw their hopes of winning a sixth World Cup ended by Croatia at Education City Stadium on Friday.
Following a goalless 90 minutes, Neymar put Tite's side in front just before half-time in extra-time. But Croatia rallied and forced penalties when Bruno Petkovic levelled four minutes from time.
The quarter-final subsequently went to spot-kicks and, after Dominik Livakovic kept out Rodrygo's effort, Marquinhos hit the post as Croatia reached the semi-final stage for the second successive tournament.
Martinelli and Gabriel Jesus each made three appearances during the World Cup.
Copyright 2023 The Arsenal Football Club plc. Permission to use quotations from this article is granted subject to appropriate credit being given to www.arsenal.com as the source.