Saturday's visitors have never won at Arsenal in any competition - losing 22 and drawing four of their 26 visits.
Arsène Wenger's team put in a much-improved performance on Tuesday, drawing 2-2 against Schalke in Germany.
Theo Walcott scored and drew praise from his manager for his display in Gelsenkirchen. He has now scored eight goals this season, despite the majority of his appearances coming as a substitute.
Thomas Vermaelen, who scored at both ends in last season's 1-1 draw here, is due a goal and looks a lively outsider at 16/1 in the first goalscorer market.
*Fancy winning 4 VIP tickets to see Arsenal v Montpellier? Open an account with GunnersGaming and you will receive an entry into the prize draw for every £10 you wager before November 18
*Odds correct at time of writing. Terms and conditions apply.9 Nov 2012